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Unified Total Syntheses of (−)‐Medicarpin, (−)‐Sophoracarpan A, and (±)‐Kushecarpin A with Some Structural Revisions
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2014-12-04 , DOI: 10.1002/anie.201408910
Zhen-Gao Feng , Wen-Ju Bai , Thomas R. R. Pettus

The total syntheses of medicarpin, sophoracarpan A, and kushecarpin A from a common intermediate are achieved by using ortho and para‐quinone methide chemistry. Additionally, the relative stereochemistry of sophoracarpan A and B have been reassigned.

中文翻译:

(−)‐ Medicarpin,(−)‐ Sophoracarpan A和(±)‐Kushecarpin A的统一总合成,并进行了一些结构修订

medicarpin,sophoracarpan A,和kushecarpin A的从一个共同的中间的全合成是通过使用邻实现-和对-醌甲基化物的化学反应。另外,槐果胶A和B的相对立体化学已被重新分配。
更新日期:2014-12-04
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