Metal–organic frameworks (MOFs) have emerged as porous solids of a superior type for the fabrication of membranes. However, it is still challenging to prepare a uniformly dispersed robust MOF hybrid membrane. Herein, we propose a simple and powerful strategy, namely, coordination‐driven in situ self‐assembly, for the fabrication of MOF hybrid membranes. On the basis of the coordination interactions between metal ions and ligands and/or the functional groups of the organic polymer, this method was confirmed to be feasible for the production of a stable membrane with greatly improved MOF‐particle dispersion in and compatibility with the polymer, thus providing outstanding separation ability. As an experimental proof of concept, a high‐quality ZIF‐8/PSS membrane was fabricated that showed excellent performance in the nanofiltration and separation of dyes from water.

中文翻译：

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协调驱动的原位自组装策略制备金属-有机骨架杂化膜

金属有机骨架（MOF）已作为一种优异的多孔固体出现，用于制造膜。然而，制备均匀分散的坚固的MOF杂化膜仍然具有挑战性。在此，我们提出了一种简单而有效的策略，即由协调驱动的原位自组装技术来制造MOF杂化膜。基于金属离子与配体和/或有机聚合物的官能团之间的配位相互作用，该方法被证实可用于生产稳定的膜，并大大改善了MOF颗粒在聚合物中的分散性并与聚合物相容，从而提供出色的分离能力。作为概念的实验证明，