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Visible-light-promoted synthesis of benzothiazoles from 2-aminothiophenols and aldehydes
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2017-02-04 07:34:45
Lin-miao Ye, Jie Chen, Peng Mao, Zhi-feng Mao, Xue-jing Zhang, Ming Yan

A visible-light-promoted synthesis of benzothiazoles from 2-aminothiophenols and aldehydes has been developed. A wide range of aromatic, heteroaromatic and aliphatic aldehydes were successfully applied. The benzothiazole products were prepared in good yields. The reaction was carried out in the absence of transition-metal catalysts and extra additives. A radical reaction pathway was proposed.

中文翻译:

可见光促进的2-氨基硫酚和醛类合成苯并噻唑的合成

已经开发了由可见光促进的由2-氨基硫酚和醛合成苯并噻唑的方法。成功地应用了各种芳香族,杂芳香族和脂肪族醛。苯并噻唑产物的制备得率很高。该反应在没有过渡金属催化剂和额外的添加剂的情况下进行。提出了自由基反应途径。
更新日期:2017-02-04
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