Rhenium‐Catalyzed Synthesis of 3‐Imino‐1‐isoindolinones by C?H Bond Activation: Application to the Synthesis of Polyimide Derivatives,Angewandte Chemie International Edition

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Rhenium‐Catalyzed Synthesis of 3‐Imino‐1‐isoindolinones by C?H Bond Activation: Application to the Synthesis of Polyimide Derivatives
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2013-09-13 , DOI: 10.1002/anie.201306360
Shunsuke Sueki _{1,

2} , Yuanfang Guo ₁ , Motomu Kanai ₁ , Yoichiro Kuninobu _{1,

2}

Affiliation

Polyimide solution: Synthesis of the title compounds from aromatic imidates and isocyanates in good to excellent yields by a rhenium‐catalyzed CH bond transformation is described. The reaction also proceeded in high yield on gram scale and could be applied to the synthesis of polyimide derivatives (see figure), which are highly soluble in organic solvents.

中文翻译：

的3-亚氨基-1-异吲铼催化合成被C ？H键活化：在合成聚酰亚胺衍生物中的应用

聚酰亚胺溶液：描述了通过aromatic催化的CH键转换，由芳族酰亚胺和异氰酸酯以良好至极好的收率合成标题化合物的方法。该反应也以克规模以高收率进行，可用于合成高度溶于有机溶剂的聚酰亚胺衍生物（见图）。

更新日期：2013-09-13

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