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Advent of 2D Rhenium Disulfide (ReS2): Fundamentals to Applications
Advanced Functional Materials ( IF 18.5 ) Pub Date : 2017-01-30 , DOI: 10.1002/adfm.201606129 Mohammad Rahman 1 , Kenneth Davey 1 , Shi-Zhang Qiao 1
Advanced Functional Materials ( IF 18.5 ) Pub Date : 2017-01-30 , DOI: 10.1002/adfm.201606129 Mohammad Rahman 1 , Kenneth Davey 1 , Shi-Zhang Qiao 1
Affiliation
Rhenium disulfide (ReS2) is a two‐dimensional (2D) group VII transition metal dichalcogenide (TMD). It is attributed with structural and vibrational anisotropy, layer‐independent electrical and optical properties, and metal‐free magnetism properties. These properties are unusual compared with more widely used group VI‐TMDs, e.g., MoS2, MoSe2, WS2 and WSe2. Consequently, it has attracted significant interest in recent years and is now being used for a variety of applications including solid state electronics, catalysis, and, energy harvesting and energy storage. It is anticipated that ReS2 has the potential to be equally used in parallel with isotropic TMDs from group VI for all known applications and beyond. Therefore, a review on ReS2 is very timely. In this first review on ReS2, we critically analyze the available synthesis procedures and their pros/cons, atomic structure and lattice symmetry, crystal structure, and growth mechanisms with an insight into the orientation and architecture of domain and grain boundaries, decoupling of structural and vibrational properties, anisotropic electrical, optical, and magnetic properties impacted by crystal imperfections, doping and adatoms adsorptions, and contemporary applications in different areas.
中文翻译:
二维二硫化R(ReS2)的出现:应用基础
二硫化hen(ReS 2)是二维(2D)的VII族过渡金属二卤化二硫化氢(TMD)。其归因于结构和振动各向异性,与层无关的电学和光学性质以及无金属的磁性质。与更广泛使用的VI-TMD组(例如MoS 2,MoSe 2,WS 2和WSe 2)相比,这些特性是不寻常的。因此,近年来,它引起了极大的兴趣,并且现在被用于各种应用,包括固态电子学,催化以及能量收集和能量存储。预计ReS 2有潜力与VI组的各向同性TMD并行使用,用于所有已知应用及以后的应用。因此,对ReS 2进行审查非常及时。在有关ReS 2的第一篇综述中,我们严格分析了可用的合成程序及其优缺点,原子结构和晶格对称性,晶体结构以及生长机制,并深入了解了畴和晶界的取向和结构,结构的解耦晶体缺陷,掺杂和吸附原子的吸附以及在不同领域的当代应用对振动性能,各向异性电,光学和磁性能的影响。
更新日期:2017-01-30
中文翻译:
二维二硫化R(ReS2)的出现:应用基础
二硫化hen(ReS 2)是二维(2D)的VII族过渡金属二卤化二硫化氢(TMD)。其归因于结构和振动各向异性,与层无关的电学和光学性质以及无金属的磁性质。与更广泛使用的VI-TMD组(例如MoS 2,MoSe 2,WS 2和WSe 2)相比,这些特性是不寻常的。因此,近年来,它引起了极大的兴趣,并且现在被用于各种应用,包括固态电子学,催化以及能量收集和能量存储。预计ReS 2有潜力与VI组的各向同性TMD并行使用,用于所有已知应用及以后的应用。因此,对ReS 2进行审查非常及时。在有关ReS 2的第一篇综述中,我们严格分析了可用的合成程序及其优缺点,原子结构和晶格对称性,晶体结构以及生长机制,并深入了解了畴和晶界的取向和结构,结构的解耦晶体缺陷,掺杂和吸附原子的吸附以及在不同领域的当代应用对振动性能,各向异性电,光学和磁性能的影响。