当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Evidence of Solubility of the Acetylide Ion C22−: Syntheses and Crystal Structures of K2C2⋅2 NH3, Rb2C2⋅2 NH3, and Cs2C2⋅7 NH3
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2012-11-19 , DOI: 10.1002/anie.201206349
Markus Hamberger , Stefan Liebig , Ute Friedrich , Nikolaus Korber , Uwe Ruschewitz

Carbon anions in solution: C22− dumbbells are well‐known in solid‐state compounds. The crystallization of the title compounds now shows that acetylide ions are existent in solution and therefore chemistry with small dissolved carbon anions may be within reach.
image


中文翻译:

乙酰胺离子C22-的溶解度证据:K2C2⋅2NH3,Rb2C2⋅2NH3和Cs2C2⋅7NH3的合成和晶体结构

溶液中的碳阴离子:C 2 2-哑铃在固态化合物中是众所周知的。现在,标题化合物的结晶表明,溶液中存在乙炔离子,因此可以实现具有少量溶解碳阴离子的化学反应。
图像
更新日期:2012-11-19
down
wechat
bug