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Zirconocene Dichloride Catalyzed Hydrodefluorination of C?F bonds
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2012-11-06 , DOI: 10.1002/anie.201207036 Shuhui Yow , Sarah J. Gates , Andrew J. P. White , Mark R. Crimmin
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2012-11-06 , DOI: 10.1002/anie.201207036 Shuhui Yow , Sarah J. Gates , Andrew J. P. White , Mark R. Crimmin
A two‐metal job: Four‐coordinate aluminum dihydrides such as 1 are reported as terminal reductants for the selective title reaction. The heterobimetallic complex 2 has been isolated and shown to be catalytically competent.
中文翻译:
的C茂锆催化加氢脱?F债
两种金属的工作:据报道,四配位的二氢化铝(如1)作为选择性标题反应的末端还原剂。杂双金属配合物2已被分离出并显示出催化能力。
更新日期:2012-11-06
中文翻译:
的C茂锆催化加氢脱?F债
两种金属的工作:据报道,四配位的二氢化铝(如1)作为选择性标题反应的末端还原剂。杂双金属配合物2已被分离出并显示出催化能力。