Ironing it out: Oxoiron(IV) porphyrin π‐cation radical complexes (see figure) serve as models for the oxidation of Cl⁻ into an active chlorinating reagent that chlorinates various organic compounds. Evidence suggests that Cl⁻ is oxidized to Cl₂ via Cl^.. The mechanism involving either direct electron transfer or iron(III) hypochlorite formation, and then homolysis of the ClO bond is discussed.

中文翻译：

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氧化铁（IV）卟啉π-阳离子自由基对氯化物的氧化和随后对有机化合物的氯化

熨烫出来：Oxoiron（IV）卟啉π-阳离子自由基复合物（见图）作为模型Cl组成的氧化^-成活性氯化试剂chlorinates各种有机化合物。有证据表明，氯^-被氧化成氯₂地通过Cl ^。。涉及的Cl的直接电子转移或铁（III）的次氯酸盐的形成，然后均裂机理 O键进行了讨论。