Highly Selective Decarbonylation of 5‐(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide,Angewandte Chemie International Edition

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Highly Selective Decarbonylation of 5‐(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2011-06-09 , DOI: 10.1002/anie.201007582
Frank M. A. Geilen ₁ , Thorsten vom Stein ₁ , Barthel Engendahl ₁ , Sonja Winterle ₁ , Marcel A. Liauw ₁ , Jürgen Klankermayer ₁ , Walter Leitner _{1,

2}

Affiliation

Less is more: The integrated development and optimization of catalysts and reaction media led to a highly selective decarbonylation of 5‐(hydroxymethyl)furfural (HMF) to furfuryl alcohol (FFA) with an iridium/phosphine catalyst in the presence of compressed carbon dioxide. Subsequent hydrogenation over ruthenium nanoparticles (RuNPs) led to tetrahydrofurfuryl alcohol (THFA), a possible solvent for the decarbonylation reaction (see scheme).

中文翻译：

压缩二氧化碳存在下5-（羟甲基）糠醛的高选择性脱羰

少即是多：催化剂和反应介质的综合开发和优化导致在压缩二氧化碳存在下，使用铱/膦催化剂将5-（羟甲基）糠醛（HMF）高度选择性地脱羰为糠醇（FFA）。随后在钌纳米颗粒（RuNPs）上进行氢化反应，生成四氢糠醇（THFA），这是脱羰反应的一种可能溶剂（参见方案）。

更新日期：2011-06-09

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