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From Discovery to Application: 50 Years of the Vinylcyclopropane–Cyclopentene Rearrangement and Its Impact on the Synthesis of Natural Products
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2010-06-16 , DOI: 10.1002/anie.200906001
Tomas Hudlicky , Josephine W. Reed

A classic that hasn't lost its charm: The historical origins and current status of the vinylcyclopropane–cyclopentene rearrangement and the corresponding transformations of heteroatom‐containing analogues (see scheme) are described in the context of methodology development and natural products synthesis. Several important events that greatly influenced the author's own research program some 30 to 40 years ago are recounted as personal recollections.
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中文翻译:

从发现到应用:乙烯基环丙烷-环戊烯重排的50年及其对天然产物合成的影响

一个没有失去魅力的经典:乙烯基环丙烷-环戊烯重排的历史起源和现状以及含杂原子的类似物的相应转化(参见方案)在方法学发展和天然产物合成的背景下进行了描述。大约在30到40年前,对作者的研究计划产生重大影响的几个重要事件被视为个人回忆。
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更新日期:2010-06-16
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