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Complex Hollow Nanostructures: Synthesis and Energy‐Related Applications
Advanced Materials ( IF 27.4 ) Pub Date : 2017-01-16 , DOI: 10.1002/adma.201604563
Le Yu 1 , Han Hu 1 , Hao Bin Wu 1 , Xiong Wen David Lou 1, 2
Affiliation  

Hollow nanostructures offer promising potential for advanced energy storage and conversion applications. In the past decade, considerable research efforts have been devoted to the design and synthesis of hollow nanostructures with high complexity by manipulating their geometric morphology, chemical composition, and building block and interior architecture to boost their electrochemical performance, fulfilling the increasing global demand for renewable and sustainable energy sources. In this Review, we present a comprehensive overview of the synthesis and energy‐related applications of complex hollow nanostructures. After a brief classification, the design and synthesis of complex hollow nanostructures are described in detail, which include hierarchical hollow spheres, hierarchical tubular structures, hollow polyhedra, and multi‐shelled hollow structures, as well as their hybrids with nanocarbon materials. Thereafter, we discuss their niche applications as electrode materials for lithium‐ion batteries and hybrid supercapacitors, sulfur hosts for lithium–sulfur batteries, and electrocatalysts for oxygen‐ and hydrogen‐involving energy conversion reactions. The potential superiorities of complex hollow nanostructures for these applications are particularly highlighted. Finally, we conclude this Review with urgent challenges and further research directions of complex hollow nanostructures for energy‐related applications.

中文翻译:

复杂的空心纳米结构:合成和与能源有关的应用

中空纳米结构为先进的能量存储和转换应用提供了有希望的潜力。在过去的十年中,通过操纵几何形状,化学成分,结构单元和内部建筑以提高其电化学性能,满足了全球对可再生能源不断增长的需求,致力于高复杂度的中空纳米结构的设计和合成方面投入了大量的研究工作。和可持续能源。在本综述中,我们对复杂的中空纳米结构的合成及其与能源相关的应用进行了全面概述。在简要分类之后,详细描述了复杂的空心纳米结构的设计和合成,其中包括分层空心球,分层管状结构,空心多面体,和多壳空心结构,以及它们与纳米碳材料的混合体。此后,我们讨论了它们的利基应用,如锂离子电池和混合超级电容器的电极材料,锂硫电池的硫基质以及涉及氧和氢的能量转化反应的电催化剂。特别强调了复杂空心纳米结构在这些应用中的潜在优势。最后,我们在本综述的结尾处提出了紧迫的挑战,并提出了用于能源相关应用的复杂中空纳米结构的进一步研究方向。以及涉及氧气和氢气的能量转换反应的电催化剂。特别强调了复杂空心纳米结构在这些应用中的潜在优势。最后,我们在本综述的结尾处提出了紧迫的挑战,并提出了用于能源相关应用的复杂中空纳米结构的进一步研究方向。以及涉及氧气和氢气的能量转换反应的电催化剂。特别强调了复杂空心纳米结构在这些应用中的潜在优势。最后,我们在本综述的结尾处提出了紧迫的挑战,并提出了用于能源相关应用的复杂中空纳米结构的进一步研究方向。
更新日期:2017-01-16
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