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Phosphonated Hexaphenylbenzene: A Crystalline Proton Conductor
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2009-11-26 , DOI: 10.1002/anie.200902116
Lucía Jiménez-García , Anke Kaltbeitzel , Wojciech Pisula , Jochen S. Gutmann , Markus Klapper , Klaus Müllen

Well stacked: Organic crystals of small molecules constitute an alternative to common polymeric electrolytes (Nafion 117) and inorganic crystals that are employed as proton exchange membranes in fuel cell systems. A phosphonic acid containing hexaphenylbenzene forms a columnar supramolecular array and exhibits a high and constant intrinsic conductivity of 3.2×10−3 S cm−1 from 120 to 180 °C under 1 bar H2O atmosphere (see picture).
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中文翻译:

膦化六苯苯:结晶质子导体

堆叠良好:小分子的有机晶体构成了普通聚合物电解质(Nafion 117)的替代品,而无机晶体则被用作燃料电池系统中的质子交换膜。含有六苯基苯的膦酸形成柱状超分子阵列,并且在1 bar H 2 O气氛下,从120到180°C ,具有恒定的3.2×10 -3  S cm -1的固有电导率(见图)。
图像
更新日期:2009-11-26
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