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Selective Synthesis of [12]Cycloparaphenylene
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2009-07-08 , DOI: 10.1002/anie.200902617
Hiroko Takaba , Haruka Omachi , Yosuke Yamamoto , Jean Bouffard , Kenichiro Itami

Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium‐catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis‐1,4‐dihydroxycyclohexane‐1,4‐diyl unit to attenuate the build‐up of strain energy during macrocyclization.
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中文翻译:

[12]环对亚苯基的选择性合成

系紧安全带:[12]碳纳米管的侧壁部分(见图)环对亚苯基是通过逐步的钯催化的偶联反应以选择性方式合成的。该合成利用顺环1,4-二羟基环己烷-1,4-二基单元在大环化过程中减弱应变能积累的能力。
图像
更新日期:2009-07-08
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