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Selective Synthesis of [12]Cycloparaphenylene
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2009-07-08 , DOI: 10.1002/anie.200902617 Hiroko Takaba , Haruka Omachi , Yosuke Yamamoto , Jean Bouffard , Kenichiro Itami
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2009-07-08 , DOI: 10.1002/anie.200902617 Hiroko Takaba , Haruka Omachi , Yosuke Yamamoto , Jean Bouffard , Kenichiro Itami
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Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium‐catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis‐1,4‐dihydroxycyclohexane‐1,4‐diyl unit to attenuate the build‐up of strain energy during macrocyclization.
中文翻译:
[12]环对亚苯基的选择性合成
系紧安全带:[12]碳纳米管的侧壁部分(见图)环对亚苯基是通过逐步的钯催化的偶联反应以选择性方式合成的。该合成利用顺环1,4-二羟基环己烷-1,4-二基单元在大环化过程中减弱应变能积累的能力。
更新日期:2009-07-08
![image image](https://wol-prod-cdn.literatumonline.com/cms/attachment/f77a61aa-95fa-4099-9b7e-9a050671d226/mcontent.gif)
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
[12]环对亚苯基的选择性合成
系紧安全带:[12]碳纳米管的侧壁部分(见图)环对亚苯基是通过逐步的钯催化的偶联反应以选择性方式合成的。该合成利用顺环1,4-二羟基环己烷-1,4-二基单元在大环化过程中减弱应变能积累的能力。
![图像 图像](https://wol-prod-cdn.literatumonline.com/cms/attachment/f77a61aa-95fa-4099-9b7e-9a050671d226/mcontent.gif)