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Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2016-12-21 02:20:44 , DOI: 10.1002/anie.201612062
Guorui Cai 1 , Hai-Long Jiang 1
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Pore size expansion and framework stability are two crucial issues, but are rarely addressed simultaneously in a single metal–organic framework (MOFs). H.-L. Jiang and G. Cai show in their Communication (10.1002/anie.201610914) that a versatile modulator-induced defect-formation strategy allows the preparation of hierarchically porous MOFs (HP-MOFs) with high stability and tailorable pore features, which enable HP-MOFs to be important porous platforms for applications involving large molecules, especially in catalysis.

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孔径扩大和框架稳定性是两个关​​键问题,但很少在单个金属有机框架(MOF)中同时解决。高 Jiang和G. Cai在其《通讯(10.1002 / anie.201610914)》中表明,一种通用的调制器诱导的缺陷形成策略可以制备具有高稳定性和可定制孔特征的分层多孔MOF(HP-MOF),从而使HP-对于涉及大分子的应用,MOF是重要的多孔平台,尤其是在催化领域。
更新日期:2016-12-21
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