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Three‐Dimensional Metal–Organic Framework as Super Heat‐Resistant Explosive: Potassium 4‐(5‐Amino‐3‐Nitro‐1H‐1,2,4‐Triazol‐1‐Yl)‐3,5‐Dinitropyrazole
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-01-16 , DOI: 10.1002/chem.201605382
Chuan Li 1 , Man Zhang 1 , Qishan Chen 1 , Yingying Li 1 , Huiqi Gao 1 , Wei Fu 1 , Zhiming Zhou 1, 2
Affiliation  

A new super heat‐resistant explosive, potassium 4‐(5‐amino‐3‐nitro‐1H‐1,2,4‐triazol‐1‐yl)‐3,5‐dinitropyrazole (KCPT, 1), featuring a three‐dimensional (3D) energetic metal–organic framework (MOF) was synthesized and fully characterized. The new 3D MOF was found to be extremely heat‐resistant, having a high decomposition temperature of 323 °C. In addition, KCPT exhibits the best calculated detonation performance (vD=8457 m s−1, p=32.5 GPa) among the reported super heat‐resistant explosives or energetic potassium salts while retaining a suitable impact sensitivity of 7.5 J, which makes it one of the most promising heat‐resistant explosives.

中文翻译:

三维金属有机框架,为超耐热炸药:钾4-(5-氨基-3-硝基-1H-1,1,2,4-三唑-1-Yl)-3,5-二硝基吡唑

一个新的超级耐热炸药,钾4-(5-氨基-3-硝基-1- ħ -1,2,4-三唑-1-基)-3,5- dinitropyrazole(KCPT,1),具有三三维(3D)高能金属-有机骨架(MOF)已合成并得到充分表征。发现新的3D MOF具有极高的耐热性,分解温度高达323°C。此外,在报道的超耐热炸药或高能钾盐中,KCPT表现出最佳的爆轰性能(v D = 8457 m s -1p = 32.5 GPa),同时保留了7.5 J的合适冲击敏感性,使其成为一种最有前途的耐热炸药。
更新日期:2017-01-16
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