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Diels-Alder reactions of 1-phenylpyrano[3,4-b]indol-3-ones with alkynes: New functionalized carbazoles
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 25 JAN 2006 , DOI: 10.1002/jlac.1990199001144 Ulf Pindur , Houshang Erfanian-Abdoust
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 25 JAN 2006 , DOI: 10.1002/jlac.1990199001144 Ulf Pindur , Houshang Erfanian-Abdoust
3-Indolylalkanoic acids 2 react with benzoic acid anhydride under catalysis of Et2O - ZnCl2 and mild conditions to furnish the 1-phenyl-substituted pyrano[3,4-b]indol-3-ones 1c, 1d, and 3a, 3b. Products 1c, 1d, and 3b may be converted into the novel functionalized carbazoles 4 and 5 by reaction with acceptor-substituted alkynes.
中文翻译:
1-苯基吡喃并[3,4- b ]吲哚-3-酮与炔烃的狄尔斯-阿尔德反应:新型官能化咔唑
3-吲哚基链烷酸2在Et 2 O-ZnCl 2的催化下和温和条件下与苯甲酸酐反应,得到1-苯基取代的吡喃并[3,4- b ]吲哚-3-酮1c,1d和3a,3b。产物1c,1d和3b可通过与受体取代的炔烃反应而转化为新型的官能化咔唑4和5。
更新日期:2017-01-31
中文翻译:
1-苯基吡喃并[3,4- b ]吲哚-3-酮与炔烃的狄尔斯-阿尔德反应:新型官能化咔唑
3-吲哚基链烷酸2在Et 2 O-ZnCl 2的催化下和温和条件下与苯甲酸酐反应,得到1-苯基取代的吡喃并[3,4- b ]吲哚-3-酮1c,1d和3a,3b。产物1c,1d和3b可通过与受体取代的炔烃反应而转化为新型的官能化咔唑4和5。