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A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene
J. Chem. Soc., Perkin Trans. 2 Pub Date : 1998 , DOI: 10.1039/a707586c Atnaf Admasu , Anna D. Gudmundsdóttir , Matthew S. Platz , David S. Watt , Stephan Kwiatkowski , Peter J. Crocker
J. Chem. Soc., Perkin Trans. 2 Pub Date : 1998 , DOI: 10.1039/a707586c Atnaf Admasu , Anna D. Gudmundsdóttir , Matthew S. Platz , David S. Watt , Stephan Kwiatkowski , Peter J. Crocker
3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser flash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.
中文翻译:
对甲苯基(三氟甲基)卡宾的激光闪光光解研究
通过激光闪光光解法(LFP)研究了3-对甲苯基-3-三氟甲基重氮基,获得了对甲苯基(三氟甲基)卡宾1的绝对动力学。1与吡啶,酮和生物猝灭剂反应的绝对速率常数。获得了兴趣。讨论了数据对光亲和标记实验的意义。
更新日期:2017-01-31
中文翻译:
对甲苯基(三氟甲基)卡宾的激光闪光光解研究
通过激光闪光光解法(LFP)研究了3-对甲苯基-3-三氟甲基重氮基,获得了对甲苯基(三氟甲基)卡宾1的绝对动力学。1与吡啶,酮和生物猝灭剂反应的绝对速率常数。获得了兴趣。讨论了数据对光亲和标记实验的意义。