PhSO2SCF2H: A Shelf‐Stable, Easily Scalable Reagent for Radical Difluoromethylthiolation,Angewandte Chemie International Edition

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PhSO2SCF2H: A Shelf‐Stable, Easily Scalable Reagent for Radical Difluoromethylthiolation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2016-11-17 , DOI: 10.1002/anie.201609468
Dianhu Zhu ₁ , Xinxin Shao ₁ , Xin Hong ₁ , Long Lu ₁ , Qilong Shen ₁

Affiliation

A new shelf‐stable and easily scalable difluoromethylthiolating reagent S‐(difluoromethyl) benzenesulfonothioate (PhSO₂SCF₂H) was developed. PhSO₂SCF₂H is a powerful reagent for radical difluoromethylthiolation of aryl and alkyl boronic acids, decarboxylative difluoromethylthiolation of aliphatic acids, and a phenylsulfonyl‐difluoromethylthio difunctionalization of alkenes under mild reaction conditions.

中文翻译：

PhSO2SCF2H：一种对二氟甲基硫代自由基自由基稳定且易于扩展的试剂

开发了一种新的货架稳定且易于扩展的二氟甲基硫醇化试剂S-（二氟甲基）苯磺酸硫（PhSO ₂ SCF ₂ H）。PhSO ₂ SCF ₂ H是用于在温和的反应条件下进行芳基和烷基硼酸的自由基二氟甲硫基化，脂肪酸的脱羧二氟甲硫基化以及烯烃的苯磺酰基-二氟甲硫基二官能化的强大试剂。

更新日期：2016-11-17

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