Intervalence Charge Transfer and Exothermic and Isoenergetic Symmetry Breaking Charge Separation in Far-Red Capturing Zinc Phthalocyanine Dimers,Angewandte Chemie International Edition

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Intervalence Charge Transfer and Exothermic and Isoenergetic Symmetry Breaking Charge Separation in Far-Red Capturing Zinc Phthalocyanine Dimers
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2025-03-18 , DOI: 10.1002/anie.202502516
Ram R Kaswan ₁ , Desiré Molina ₂ , Lydia Ferrer-López ₂ , Javier Ortiz ₂ , Paul A Karr ₃ , Ángela Sastre-Santos ₂ , Francis D'Souza ₁

Affiliation

The occurrence of intervalence charge transfer and exothermic and isoenergetic symmetry-breaking charge separation in far-red capturing zinc phthalocyanine dimers is demonstrated. Further, the splitting of redox peak and near-infrared intervalence charge transfer (IVCT) signal have been used as diagnostic markers to prove the IVCT mechanism and occurrence of symmetry-breaking charge separation (SB-CS) in newly synthesized identical pairs of ZnPc chromophores.

中文翻译：

远红外捕获锌酞菁二聚体中的间隔电荷转移以及放热和等能对称性断裂电荷分离

证明了在远红外捕获锌酞菁二聚体中间隔电荷转移以及放热和等能对称性破坏电荷分离的发生。此外，氧化还原峰的分裂和近红外间隔电荷转移（IVCT）信号已被用作诊断标志物，以证明新合成的相同 ZnPc 发色团对中 IVCT 机制和对称破坏电荷分离（SB-CS）的发生。

更新日期：2025-03-18

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