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An Efficient Total Synthesis of Decarestrictine D
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2008-03-01 , DOI: 10.1002/ejoc.200700868
Priti Gupta , Pradeep Kumar

An efficient total synthesis of decarestrictine D has been achieved using cross-metathesis or ring-closing metathesis and Yamaguchi macrolactonization as key steps. The stereogenic centres were generated by means of hydrolytic kinetic resolution (HKR) and Sharpless asymmetric dihydroxylation (AD). (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

中文翻译:

Decarestrictine D 的有效全合成

使用交叉复分解或闭环复分解和 Yamaguchi 大环内酯化作为关键步骤,已经实现了去卡勒烯 D 的有效全合成。立体中心是通过水解动力学拆分 (HKR) 和 Sharpless 不对称二羟基化 (AD) 产生的。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
更新日期:2008-03-01
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