Single-Electron-Transfer-Mediated Carbonylation Reactions,Accounts of Chemical Research

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Single-Electron-Transfer-Mediated Carbonylation Reactions
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2025-03-05 , DOI: 10.1021/acs.accounts.5c00039
Le-Cheng Wang _{1,

2} , Xiao-Feng Wu _{1,

2}

Affiliation

Transition-metal-catalyzed carbonylation coupling methods have been accepted as an essential tool for producing carbonylated products over the past few decades. Despite its long-standing history and widespread industrial applications, several challenges remain in carbonylation chemistry. These include reliance on precious metal catalysts, the need of high-energy radiation, difficulties in carbonylation of unactivated chemical bonds, etc. As an alternative to classic two-electron transfer process, single-electron-transfer (SET)-mediated carbonylation has emerged as a powerful tool to achieve elusive carbonylation transformations. Over the past few years, carbonylation of commonly available functional handles, such as alkenes and alkyl halides, via the single-electron pathway has emerged as a valuable area of research.

中文翻译：

单电子转移介导的羰基化反应

在过去的几十年里，过渡金属催化的羰基化偶联方法已被接受为生产羰基化产品的重要工具。尽管羰基化化学历史悠久且工业应用广泛，但羰基化化学仍然存在一些挑战。这些包括对贵金属催化剂的依赖、高能辐射的需要、未活化化学键羰基化的困难等。作为经典双电子转移工艺的替代方案，单电子转移（SET）介导的羰基化已成为实现难以捉摸的羰基化转变的有力工具。在过去的几年里，通过单电子途径对常见的官能团手柄（如烯烃和烷基卤化物）进行羰基化已成为一个有价值的研究领域。

更新日期：2025-03-05

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