当前位置: X-MOL 学术 › J. Chem. Soc., Perkin Trans. 1 › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
General synthesis of methyl- and dimethyl -cyclobutanes from simple 1,3-diols by phase transfer catalysis
Journal of the Chemical Society, Perkin Transactions 1 Pub Date : 1993 , DOI: 10.1039/p19930000801
Béla Török , Árpád Molnár

A general method is described for the preparation of methyl- and dimethyl-cyclobutanes from simple 1,3-diols. The key steps of the procedure are a phase transfer catalysed ring closure and the transformation of a carboxyl group to a methyl group. Phase transfer catalysis provides good yields in the synthesis of the cyclobutane skeleton.

中文翻译:

相转移催化从简单的1,3-二醇合成甲基和二甲基环丁烷

描述了由简单的1,3-二醇制备甲基和二甲基环丁烷的通用方法。该方法的关键步骤是相转移催化的闭环和羧基向甲基的转化。相转移催化在环丁烷骨架的合成中提供了良好的产率。
更新日期:2017-01-31
down
wechat
bug