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Recent advances in Fe-based metal-organic frameworks: Structural features, synthetic strategies and applications
Coordination Chemistry Reviews ( IF 20.3 ) Pub Date : 2025-01-28 , DOI: 10.1016/j.ccr.2025.216467
Keaoleboga Mosupi, Mike Masukume, Guoming Weng, Nicholas M. Musyoka, Henrietta W. Langmi

Metal organic frameworks (MOFs) are very exciting porous materials owing to their unique properties such as high surface areas, high pore volume, tunable functionalities and great thermal stabilities. The properties of MOFs can be diversely constructed by precise control of synthesis conditions. Amongst the thousands of MOFs that have been discovered to date, Fe-MOFs make up a percentage of these MOFs. Fe-MOFs are increasingly gaining great interest due to their unique properties and chemical versatility. However, comprehensive reviews on their emerging architectural features and designs as well as strategies for tailoring their applications. Therefore, in this review, we present a panoptic summary of the recent developments of Fe-MOFs, which includes synthetic strategies, activation methods, functionalization, overview of selected applications, current challenges impeding their commercialization, and suggested remedial actions. A holistic view of the interconnectedness of Fe-MOFs structural features, synthetic strategies and applications provides greater insights that highlight challenges hindering their wide-scale industrial applications. Moreover, newer approaches such as utilization of machine learning technique that are providing an opportunity for out-of-sight insights for material design and prediction of material properties are briefly highlighted. Remedial actions for challenges of transitioning Fe-based MOFs towards commercialization and industrial applications are also explored, and suggestions for these aspects are presented.

中文翻译:


铁基金属有机框架的研究进展:结构特征、合成策略及应用



金属有机框架 (MOF) 因其独特的特性(如高表面积、高孔隙体积、可调功能和出色的热稳定性)而成为非常令人兴奋的多孔材料。通过精确控制合成条件,可以构建 MOF 的特性。在迄今为止发现的数千种 MOF 中,Fe-MOF 占这些 MOF 的一定比例。Fe-MOF 因其独特的特性和化学多功能性而越来越受到极大的关注。但是,全面回顾了他们新兴的架构特征和设计以及定制其应用程序的策略。因此,在这篇综述中,我们对 Fe-MOF 的最新发展进行了全景总结,其中包括合成策略、活化方法、功能化、所选应用概述、阻碍其商业化的当前挑战以及建议的补救措施。对 Fe-MOF 结构特征、合成策略和应用相互关联的整体认识提供了更深入的见解,突出了阻碍其大规模工业应用的挑战。此外,还简要强调了较新的方法,例如利用机器学习技术,这些方法为材料设计和材料特性预测提供了不可见的见解。还探讨了应对铁基 MOF 向商业化和工业应用过渡所面临的挑战的补救措施,并提出了这些方面的建议。
更新日期:2025-01-28
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