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Copper-mediated alkylation of furan and thiophene derivatives with cyclic ethers
Tetrahedron ( IF 2.1 ) Pub Date : 2016-11-12 14:26:51 Chenyang Wang, Ming Gong, Mengmeng Huang, Yabo Li, Jung Keun Kim, Yangjie Wu
Tetrahedron ( IF 2.1 ) Pub Date : 2016-11-12 14:26:51 Chenyang Wang, Ming Gong, Mengmeng Huang, Yabo Li, Jung Keun Kim, Yangjie Wu
An efficient and complementary copper-catalyzed alkylation of (benzo)furans/(benzo)thiophenes with cyclic ethers was reported. A broad range of C2 heteroaryl-substituted cyclic ethers were obtained in moderate to good yields. The results of control experiments indicated that this transformation might proceed via a radical process.
中文翻译:
铜与呋喃和噻吩衍生物与环醚的铜介导烷基化
报道了用环醚有效和互补的铜催化的(苯并呋喃)/(苯并)噻吩的烷基化。以中等至良好的产率获得了广泛的C 2杂芳基取代的环状醚。对照实验的结果表明,这种转变可能是通过根本过程进行的。
更新日期:2016-11-13
中文翻译:
铜与呋喃和噻吩衍生物与环醚的铜介导烷基化
报道了用环醚有效和互补的铜催化的(苯并呋喃)/(苯并)噻吩的烷基化。以中等至良好的产率获得了广泛的C 2杂芳基取代的环状醚。对照实验的结果表明,这种转变可能是通过根本过程进行的。