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Ionic liquids: The emerging “cardiotonic” for photocatalytic materials
Coordination Chemistry Reviews ( IF 20.3 ) Pub Date : 2025-01-24 , DOI: 10.1016/j.ccr.2025.216461
Bin He, Sheng Zhong, Kexin Li, Shuang Wei, Mengyue Li, Ruixia Liu

Photocatalysis has been regarded as “21st century dream technology” and inspired increasing scientific interest due to their environmental and economic applicability. Due to the bottlenecks of photocatalytic materials (PMs) faced, such as low carrier separation efficiency, insufficient active sites, and incompatibility between surface interface properties and targeted reaction, restricting its advance from laboratory to application. The emergence of ionic liquids (ILs) provides a favorable term for the development of PMs due to their tailorability and diversity. This review starts with the properties of ILs (hydrogen bonds effect, electrostatic effect, polarity effect, and coordination effect), followed by analyzing the potential of ILs in PMs modification. Specifically, this review systematically summarized the regulatory mechanisms and unique advantages of ILs on the particle size, morphology, electron transport and interface properties of PMs. Finally, a summary and outlook on the major challenges, opportunities for future research in high-powered PMs by the strategy of ILs modification was proposed.

中文翻译:


离子液体:用于光催化材料的新兴“心脏强音”



光催化被认为是“21 世纪的梦想技术”,由于其环境和经济适用性,激发了越来越多的科学兴趣。由于光催化材料 (PMs) 面临的载流子分离效率低、活性位点不足、表面界面性质与靶向反应不相容等瓶颈,限制了其从实验室走向应用的进程。离子液体 (IL) 的出现因其可定制性和多样性而为 PM 的发展提供了一个有利的术语。本文从 ILs 的性质 (氢键效应、静电效应、极性效应和配位效应) 开始,然后分析 ILs 在 PM 修饰中的潜力。具体来说,本文系统总结了 ILs 对 PM 粒径、形态、电子传输和界面特性的调控机制和独特优势。最后,总结并展望了 ILs 修饰策略对高功率 PM 的主要挑战和未来研究的机遇。
更新日期:2025-01-24
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