Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle,Advanced Materials

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Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle
Advanced Materials ( IF 27.4 ) Pub Date : 2016-11-11 , DOI: 10.1002/adma.201604799
Di Bao _{1,

2} , Qi Zhang ₂ , Fan-Lu Meng _{1,

2} , Hai-Xia Zhong _{2,

3} , Miao-Miao Shi _{1,

2} , Yu Zhang ₄ , Jun-Min Yan ₁ , Qing Jiang ₁ , Xin-Bo Zhang ₂

Affiliation

Using tetrahexahedral gold nanorods as a heterogeneous electrocatalyst, an electrocatalytic N₂ reduction reaction is shown to be possible at room temperature and atmospheric pressure, with a high Faradic efficiency up to 4.02% at −0.2 V vs reversible hydrogen electrode (1.648 µg h⁻¹ cm⁻² and 0.102 µg h⁻¹ cm⁻² for NH₃ and N₂H₄·H₂O, respectively).

中文翻译：

人工条件下固氮和利用N2 / NH3循环可再生能量存储在环境条件下对N2的电化学还原

使用四面体金纳米棒作为非均相电催化剂，表明在室温和大气压下可以进行电催化的N ₂还原反应，与可逆氢电极（1.648 µg h ^{-1）相比，}在-0.2 V时法拉第效率高达4.02％对于NH ₃和N ₂ H ₄ ·H ₂ O分别为cm ^-2和0.102 µg h ^-1 cm ^-2）。

更新日期：2016-11-11

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