This study focuses on the selective epoxidation of linalool to produce linalool epoxide, a valuable intermediate for the synthesis of novel linalool‐derived compounds. A robust and non‐noble cobalt catalyst was employed to achieve high yields of linalool epoxide under mild reaction conditions. The catalytic system displayed remarkable efficiency and reusability, providing a platform for exploring different feedstock, including rosewood oil, to demonstrate its versatility in raw feedstock valorization. Further functionalization of linalool‐derived molecules was achieved through regioselective ring‐opening reactions, yielding novel ethers with potential applications in the fine chemical industry. In summary, this study presents a comprehensive approach to the sustainable synthesis of linalool‐derived compounds, displaying the versatility of the catalytic system and providing a basis for the development of novel fine organic compounds with potential industrial applications.

中文翻译：

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通过催化环氧化和开环合成芳樟醇衍生化合物的通用方法


本研究的重点是芳樟醇的选择性环氧化以产生芳樟醇环氧化物，这是一种合成新型芳樟醇衍生化合物的宝贵中间体。采用稳健的非贵金属钴催化剂在温和的反应条件下实现芳樟醇环氧化物的高产率。该催化系统表现出卓越的效率和可重复使用性，为探索包括红木油在内的不同原料提供了一个平台，以展示其在原料增值方面的多功能性。通过区域选择性开环反应实现了芳樟醇衍生分子的进一步功能化，产生了在精细化工中具有潜在应用的新型醚。总之，本研究提出了一种可持续合成芳樟醇衍生化合物的综合方法，展示了催化系统的多功能性，并为开发具有潜在工业应用的新型精细有机化合物提供了基础。