当前位置: X-MOL 学术J. Am. Chem. Soc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2014-10-31 , DOI: 10.1021/ja508829x
Tayseer Mahdi 1 , Douglas W. Stephan 1, 2
Affiliation  

Hydrogenation of alkyl and aryl ketones using H2 is catalytically achieved in 18 examples using 5 mol % B(C6F5)3 in an ethereal solvent. In these cases the borane and ether behave as a frustrated Lewis pair to activate H2 and effect the reduction.

中文翻译:

通过受挫的路易斯对实现催化酮加氢

在18个实施例中,使用在醚溶剂中的5mol% B(C6F5)3催化地实现使用H2的烷基和芳基酮的氢化。在这些情况下,硼烷和乙醚充当受挫的路易斯对来激活 H2 并实现还原。
更新日期:2014-10-31
down
wechat
bug