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Hybrid improper ferroelectricity in a Si-compatible CeO2/HfO2 artificial superlattice
npj Computational Materials ( IF 9.4 ) Pub Date : 2024-12-19 , DOI: 10.1038/s41524-024-01487-0
Pawan Kumar, Jun Hee Lee

Hybrid improper ferroelectrics (HIFs), characterized by ferroelectric polarization arising from the rotation of two symmetry inequivalent antiferrodistortive modes, exhibit exotic properties such as T-independent dielectric constants and robustness against depolarizing field. Here, using first-principles simulations, we report a new \(P{2}_{1}\) phase in a Si-compatible CeO2/HfO2 superlattice that exhibits remarkably robust hybrid improper ferroelectricity, induced by the in-plane oxygen rotations of two antiferrodistortive distortion modes. These non-polar distortions are coupled with a polar distortion through a trilinear coupling in the superlattice, stabilizing ferroelectricity as the competing ground state with the assistance of epitaxial strain. The estimated out-of-plane polarization (\(P=30.3\,\mu C/c{m}^{2}\)) is switchable with a remarkably small energy barrier of 8.5 meV/atom and relatively smaller coercive field relative to bulk HfO2, expected to reduce the operational voltage of ferroelectric devices. Our discovery may offer unexpected opportunities for innovating high-performance, low-voltage devices, and promising advancements in next-generation CMOS compatible oxide-based electronics.

更新日期:2024-12-20
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