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New Frontiers in Nitramine Reactivity via the Mitsunobu Reaction
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2024-12-19 , DOI: 10.1021/acs.joc.4c02261 Aleksei B. Sheremetev, Pavel S. Gribov, Daniil A. Chernyshov, Dmitry L. Lipilin, Kyrill Yu. Suponitsky
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2024-12-19 , DOI: 10.1021/acs.joc.4c02261 Aleksei B. Sheremetev, Pavel S. Gribov, Daniil A. Chernyshov, Dmitry L. Lipilin, Kyrill Yu. Suponitsky
N-Nitro derivatives of primary alkyl, aryl and heteroarylamines can be directly alkylated with functionalized alcohols under Mitsunobu conditions at the N and/or O atoms of the nitramino moiety to give secondary nitramines or 1-alkoxydiazene 1-oxides, respectively.
更新日期:2024-12-20