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Photoinduced Ligand-to-Metal Charge Transfer (LMCT) in Organic Synthesis: Reaction Modes and Research Advances
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-20 , DOI: 10.1039/d4cc06099g Yingying Yang, Xinxiang Huang, Yi Jin
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-20 , DOI: 10.1039/d4cc06099g Yingying Yang, Xinxiang Huang, Yi Jin
In recent years, visible light-induced ligand-to-metal charge transfer (LMCT) has emerged as an attractive approach for synthesizing a range of functionalized molecules. Compared to conventional photoredox reactions, photoinduced LMCT activation does not depend on redox potential and offers diverse reaction pathways, making it particularly suitable for the activation of inert bonds and the functional modification of complex organic molecules. This review highlights the indispensabl role of photoinduced LMCT in synthetic chemistry, with a focus on recent advancements in LMCT-mediated hydrogen atom transfer (HAT), C-C bond cleavage, decarboxylative transformations, and radical ligand transfer (RLT) reactions.
更新日期：2024-12-20
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