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Photoredox Radical/Polar Crossover Enables Carbo-Heterofunctionalization of Alkenes: Facile Access to 1,3-Difunctionalized Nitro Compounds
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-20 , DOI: 10.1039/d4cc06005a Subrata J. Patra, Vasiliki Valsamidou, Bhargav Nandasana, Dmitry Katayev
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-20 , DOI: 10.1039/d4cc06005a Subrata J. Patra, Vasiliki Valsamidou, Bhargav Nandasana, Dmitry Katayev
Herein, we present an efficient and practical method for multicomponent carbo-heterofunctionalization of alkenes via radical-polar crossover photoredox catalysis. Employing geminal bromonitroalkanes as redox-active reagents with a wide range of O-centered nucleophiles allows rapid access to various 1,3- difunctionalized nitro compounds, including β-nitro ketones, 1,3-nitro alcohols, 1,3-nitro ethers as well as cyclic molecules.
更新日期：2024-12-20
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