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β-Stereoselective Kdo C-glycosylation by (p-Tol)2SO/Tf2O preactivation strategy
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-20 , DOI: 10.1039/d4cc06149g Jing-dong Zhang, Guang-Jian Liu, Guo-Wen Xing
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-20 , DOI: 10.1039/d4cc06149g Jing-dong Zhang, Guang-Jian Liu, Guo-Wen Xing
There was very little research on the synthesis of β-3-Deoxy-D-manno-oct-2-ulosonic acid (Kdo) C-glycosides, which restricted their wide applications. Herein, a convenient and efficient approach to synthesize β-Kdo C-glycosides was developedbased on Tf2O/(p-Tol)2SO preactivation strategy using bench stable peracetylated Kdo thioglycoside as donor via a thermodynamic SN1-like mechanism.
更新日期：2024-12-20
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