Fluorination from Surface to Bulk Stabilizing High Nickel Cathode Materials with Outstanding Electrochemical Performance,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Fluorination from Surface to Bulk Stabilizing High Nickel Cathode Materials with Outstanding Electrochemical Performance
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-12-19 , DOI: 10.1002/anie.202420413
Jieyu Yang, Guihong Mao, Tengyu Yao, Laifa Shen, Yan Yu

Through interfacial fluorination and introducing F ions to bulk phase as anchors, the high-voltage high-rate cycling performance of high nickel cathodes is boosted. The fluorinated surface induces the formation of a thin, dense CEI layer to facilitate Li⁺ migration and hinder electrolyte erosion. Additionally, the substitution of F for O in bulk phase forms strong TM−F bonds, thereby enhancing surface and internal structural stability, and hindering the formation of microcracks and gas evolution.

更新日期：2024-12-20

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南