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Chemocatalytic Conversion of Dinitrogen to Ammonia Mediated by a Tungsten Complex
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-12-17 , DOI: 10.1002/anie.202420220
Anna-Marlene Vogt, Tobias A. Engesser, Jan Krahmer, Niels Michaelis, Mareike Pfeil, Jannik Junge, Christian Näther, Nicolas Le Poul, Felix Tuczek

The first tungsten complex capable of chemocatalyzing the conversion of N2 into NH3 is presented. The tungsten center is coordinated by a pentadentate tetrapodal (pentaPod/P5) phosphine ligand. By integrating a phospholano (Pln) group into the ligand structure we succeeded in obtaining the catalyst [W(N2)P5Pln]. Further investigations on the influence of the new P5Pln ligand on the catalytic ability of this tungsten complex were done.

中文翻译:


钨配合物介导的二氮向氨的化学催化转化



提出了第一个能够化学催化 N2 转化为 NH3 的钨配合物。钨中心由五齿四足 (pentaPod/P5) 膦配体配位。通过将磷酸醛酸 (Pln) 基团整合到配体结构中,我们成功获得了催化剂 [W(N,2)P5,Pln]。对新的 P5Pln 配体对这种钨配合物催化能力的影响进行了进一步的研究。
更新日期:2024-12-17
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