Ligand-Protected Golden Fullerene Au42 with Unprecedented Metal Coordination Number of 15,Angewandte Chemie International Edition

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Ligand-Protected Golden Fullerene Au42 with Unprecedented Metal Coordination Number of 15
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-12-16 , DOI: 10.1002/anie.202417904
Heng-Wang Luyang ₁ , Cong-Qiao Xu ₂ , Shang-Fu Yuan ₁ , Jun Li _{1,

2} , Quan-Ming Wang ₁

Affiliation

A “golden fullerene” Au₄₂ cluster topologically related to D_3h C₇₈ has a centered core–shell structure Au@Au₁₅@Au₂₆ featuring record high metal coordination number of 15. Its excellent stability is attributed to both the superatomic characteristics of the Au₄₂ kernel and the gold-ligand interactions.

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