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Charge-dependent hierarchical self-assembling of fluorinated gold nanoclusters
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-16 , DOI: 10.1039/d4cc04786a
Yuki Saito, Duhong Sun, Hayato Kanai, Yasuhiro Ishida, Hideyuki Mitomo, Kuniharu Ijiro, Katsuaki Konishi

Au25(SR)18 nanoclusters decorated with semifluorinated thiolate ligands (SFLs) self-assemble hierarchically depending on the charge state of the nanocluster component; the use of the anionic cluster ([Au25]) resulted in the generation of nanofibers, whereas the neutral counterpart ([Au25]0) gave micron-sized filaments as a result of the bundling/twisting of the nanofibers.

中文翻译:


氟化金簇的电荷依赖性分层自组装



由半氟化硫代配体 (SFL) 修饰的 Au25(SR)18 纳米团簇根据纳米团簇组分的电荷状态进行分层自组装;使用阴离子簇 ([Au25]–) 导致纳米纤维的产生,而中性对应物 ([Au25]0) 由于纳米纤维的扭曲而产生微米级的细丝。
更新日期:2024-12-20
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