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Performance and hydration mechanisms of ultrafine iron ore tailings enhanced supersulfated cement with high phosphogypsum content
Cement and Concrete Composites ( IF 10.8 ) Pub Date : 2024-12-13 , DOI: 10.1016/j.cemconcomp.2024.105891
Mingzhe Zhang, Bing Chen, Weisheng Zhu

This study systematically investigates the influence of ultrafine iron ore tailings (UIOT) on the performance and hydration process of supersulfated cement (SSC) with high phosphogypsum (PG) content. UIOT incorporation retards early-age strength but enhances later-age strength, with a 20 % replacement ratio of granulated blast furnace slag (GBFS) leading to a 52 % increase in 28-day compressive strength. The performance improvement can be primarily attributed to the following aspects: in the first instance, UIOT regulates the formation rate of ettringite (AFt) by promoting the formation of Fe-Al-bearing AFt ((Fe, Al)-AFt), thereby reducing the excessive formation of AFt typically observed in high-gypsum blended systems. Furthermore, UIOT promotes the formation of calcium-alumino-silicate hydrate (C-(A)-S-H) gel and optimizes the Si/Ca ratio of the gel. The unreacted UIOT particles also play a physical filling role, contributing to the performance enhancement.

中文翻译:


高磷石膏含量超细铁矿石尾矿强化超硫酸化水泥的性能及水化机理



本研究系统研究了超细铁矿石尾矿 (UIOT) 对高磷石膏 (PG) 含量的超硫酸化水泥 (SSC) 性能和水化过程的影响。UIOT 掺入延缓了早期强度,但增强了晚期强度,粒化高炉渣 (GBFS) 的替代率为 20%,导致 28 天抗压强度提高了 52%。性能改进主要归因于以下几个方面:首先,UIOT 通过促进含 Fe-Al 的 AFt ((Fe, Al)-AFt) 的形成来调节钙矾石 (AFt) 的形成,从而减少通常在高石膏混合系统中观察到的 AFt 的过度形成。此外,UIOT 促进钙-铝-硅酸盐水合物 (C-(A)-S-H) 凝胶的形成,并优化凝胶的 Si/Ca 比率。未反应的 UIOT 颗粒也起到物理填充作用,有助于性能增强。
更新日期:2024-12-13
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