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A hydrogen-bridged bis(silylene) complex as a platform for small molecule activation via adjacent metal–ligand cooperation
Dalton Transactions ( IF 3.5 ) Pub Date : 2024-12-13 , DOI: 10.1039/d4dt03226h
Hisako Hashimoto, Satomi Matsuo, Yuto Odagiri, Hiromi Tobita

Effective activation of small molecules (alcohol, phenol, ketones, amine, etc.) by a hydrogen-bridged bis(silylene) complex, which has two adjacent Lewis acidic centers and a hydridic bridging hydrogen with weak Si⋯H bonds, is described, along with product characterization by NMR and X-ray diffraction studies.

中文翻译:


氢桥双(硅烯)配合物作为通过相邻金属-配体合作进行小分子活化的平台



描述了氢桥双(硅烯)络合物对小分子(醇、苯酚、酮、胺)的有效活化,该络合物具有两个相邻的路易斯酸性中心和一个具有弱 Si⋯H 键的氢化桥氢,以及通过 NMR 和 X 射线衍射研究进行产品表征。
更新日期:2024-12-13
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