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A series of isostructural polyoxometalate-based metal–organic frameworks of 3,5-bis(1′,2′,4′-triazol-1′-yl)pyridine: synthesis, structures and electrocatalytic properties
Dalton Transactions ( IF 3.5 ) Pub Date : 2024-12-11 , DOI: 10.1039/d4dt02945c
Tinghui Xie, Xinfang Wang, Tingting Cao, Zuogang Huang, Huaguang Yu

Three isostructural polyoxometalate-based metal–organic frameworks (POMOFs) [MII2(btap)2(β-Mo8O26)(H2O)4]·4H2O (M = Co 1, Ni 2, Zn 3) based on octamolybdate and 3,5-bis(1′,2′,4′-triazol-1′-yl)pyridine (btap) were synthesized via the hydrothermal method. POMOFs 1 and 2 and their thermal derivatives could be utilized as efficient electrocatalysts for the oxygen evolution reaction.

中文翻译:


3,5-双(1′,2′,4′-三唑-1′-基)吡啶的一系列等结构多金属氧酸盐基金属有机框架:合成、结构和电催化性质



三种基于八钼酸盐的等结构多金属氧酸盐基金属有机框架 (POMOF) [MII2(btap)2(β-Mo8O26)(H2O)4]·4H2O (M = Co 1, Ni 2, Zn 3) 基于八钼酸盐和 3,5-双(1′,2′,4′-三唑-1′-基)吡啶 (btap) 通过水热法合成。POMOFs 12 及其热衍生物可用作析氧反应的高效电催化剂。
更新日期:2024-12-11
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