A series of four new copper and silver-thiolate, [M(m-SPhCO₂R)]_n (M = Cu, Ag and R = H, Me), coordination polymers is reported. The study shows that the hydrogen bonding between the carboxylic acids directs the formation of a 2D structure associated with poor photoemission, while the steric hindrance of the ester groups allows the assembly of a 1D network coupled with bright luminescence.

中文翻译：

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铜和硫化银配位聚合物的 1D/2D 维数对其光物理性能的影响


报道了四种新型铜和硫代银 [M（m-SPhCO₂R）]_n （M = Cu， Ag 和 R = H， Me） 配位聚合物的系列。研究表明，羧酸之间的氢键指导与光发射不良相关的 2D 结构的形成，而酯基的空间位阻允许组装与明亮发光耦合的 1D 网络。