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A sandwich-like heterometallic Fe7Sn6 oxo cluster constructed by tessellation of an Anderson-like {Fe7} wheel for near-infrared photothermal conversion
Chemical Communications ( IF 4.3 ) Pub Date : 2024-12-10 , DOI: 10.1039/d4cc05796a
Xiu-Juan Tian, Qian Lu, Shi-Li Li, Xian-Ming Zhang

Herein we report a unique sandwich-like heterometallic Fe7Sn6 oxo cluster, which features an Anderson-type {Fe7} wheel sandwiched by two {Sn3} layers and is formed via the coordination-induced effect of 2,6-pyridinedicarboxylate. The highly efficient photothermal conversion capability and excellent photothermal stability of Fe7Sn6 demonstrate the potential for solar energy conversion.

中文翻译:


通过类似安德森的 {Fe7} 轮的镶嵌构建而成的三明治状异金属 Fe7Sn6 氧基簇,用于近红外光热转换



在此,我们报道了一种独特的三明治状异金属 Fe7Sn6 氧基簇,其特点是安德森型 {Fe7} 轮夹在两个 {Sn3} 层中,是通过 2,6-吡啶二羧酸盐的配位诱导效应形成的。Fe7Sn6 的高效光热转换能力和出色的光热稳定性证明了太阳能转换的潜力。
更新日期:2024-12-10
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