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Of perfluorinated aryllead(II) complexes
Dalton Transactions ( IF 3.5 ) Pub Date : 2024-12-09 , DOI: 10.1039/d4dt03167a
Adrian-Alexandru Someşan, Thierry Roisnel, Yann Sarazin

The pentafluorophenyl moiety C6F5 was succesfully employed for the first time in lead(II) chemistry. We are reporting on the stable and soluble organolead(II) polymer [Pb(C6F5)2(dx)] (dx = dioxane). An example of a Pb(II) “ate” complex paired with a trimetallic magnesium cation is also presented. Our foray into related tin(II) chemistry shows that this behaviour cannot be extended to the lighter tetrel, and is specific to lead(II).

中文翻译:


全氟芳基铅 (II) 络合物



五氟苯基部分 C6F5 首次成功用于铅 (II) 化学。我们正在报道稳定且可溶的有机铅 (II) 聚合物 [Pb(C6, F52(dx)] (dx = 二恶烷)。还介绍了 Pb(II) “ate”配合物与三金属镁阳离子配对的一个例子。我们对相关锡 (II) 化学的尝试表明,这种行为不能扩展到较轻的四层,并且是铅 (II) 特有的。
更新日期:2024-12-09
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