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Single-atom catalysts in the catalytic production of H2O2
Journal of Materiomics ( IF 8.4 ) Pub Date : 2024-12-08 , DOI: 10.1016/j.jmat.2024.100982
Zhiqi Li, Zhihan Yu, Chen Guan, Kaiqiang Xu, Quanjun Xiang

: As an eco-friendly oxidant, hydrogen peroxide (H2O2) has been extensively applied in many fields, such as chemical synthesis, waste water purification, medical sterilization, paper manufacture and so on. H2O2 production also suffers from various shortcomings, including bad stability and low yield. Because of the extraordinary catalytic activity of H2O2 photocatalysis and electrocatalysis, single atom catalysts (SACs) have received considerable attention in recent years. With SACs’ distinct benefits, SACs holds a significant place in the production of H2O2. It is extensively applicable to diverse reaction pathways, such as photocatalysis and electrocatalysis, which offer novel insights and a wide range of possibilities for the effective and environmentally friendly synthesis of H2O2. Appropriately reviewing and summarizing the previous and current findings is essential to advancing the study's depth. Therefore, this review emphasizes the recent progress of SACs employed for photocatalytic and electrocatalytic production of H2O2. It first presents the mechanism and benefits of SACs in the catalytic production of H2O2. Next, based on the various benefits that SACs embody in the catalytic production of H2O2, an overview of SACs systems for H2O2 production is provided, with a focus on the modulation of adsorption capacity by SACs and the inhibition of side reactions. Lastly, some difficulties of photocatalytic and electrocatalytic production of H2O2 by SACs are depicted, and future directions of development are envisioned.

中文翻译:


催化生产 H2O2 中的单原子催化剂



:过氧化氢 (H2O2) 作为一种环保型氧化剂,已广泛应用于化学合成、废水净化、医疗灭菌、造纸等许多领域。H2O2 生产还存在各种缺点,包括稳定性差和产量低。由于 H2O2 光催化和电催化具有非凡的催化活性,单原子催化剂 (SAC) 近年来受到了相当大的关注。由于 SAC 具有独特的优势,SAC 在 H2O2 的生产中占有重要地位。它广泛适用于多种反应途径,如光催化和电催化,为有效和环保合成 H2O2 提供了新颖的见解和广泛的可能性。适当地回顾和总结以前和现在的发现对于提高研究的深度至关重要。因此,本文重点介绍了 SACs 用于光催化和电催化生产 H2O2 的最新进展。它首先介绍了 SAC 在 H2O2 催化生产中的机制和优势。接下来,基于 SAC 在 H2O2 催化生产中体现的各种优势,概述了用于 H2O2 生产的 SAC 系统,重点是 SAC 对吸附能力的调节和副反应的抑制。 最后,描述了 SACs 光催化和电催化生产 H2O2 的一些困难,并设想了未来的发展方向。
更新日期:2024-12-09
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