For the first time, the cage-confinement effect is established to exploit new high-T_c ferroelectrics, of which the T_c is dramatically promoted to 402 K (>BaTiO₃, 393 K). Further, Deep understanding of cage-confinement effect and high-T_c ferroelectricity is well elaborated by combining in situ solid-state NMR spectroscopy and theoretical calculations on potential energies. This paves a new pathway and makes a breakthrough in the field of molecular ferroelectrics.

中文翻译：

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解锁笼限阳离子分子动力学对高 Tc 钙钛矿铁电体的分子动力学


首次建立了笼式限制效应以利用新的高 T_c 铁电体，其中 T_c 急剧提高到 402 K（>BaTiO₃， 393 K）。此外，通过将原位固体 NMR 波谱和势能理论计算相结合，很好地阐述了对笼式约束效应和高 T_c 铁电性的深刻理解。这为分子铁电体领域铺平了一条新的途径并取得了突破。