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Ligand Engineering Achieves Suppression of Temperature Quenching in Pure Green Perovskite Nanocrystals for Efficient and Thermostable Electroluminescence
Nano-Micro Letters ( IF 31.6 ) Pub Date : 2024-11-28 , DOI: 10.1007/s40820-024-01564-5
Kaiwang Chen, Qing Du, Qiufen Cao, Chao Du, Shangwei Feng, Yutong Pan, Yue Liang, Lei Wang, Jiangshan Chen, Dongge Ma

  • The innovative synthesis of pure green FAPbBr3 nanocrystals at room temperature was exploited by employing aromatic amine ligands to refine the perovskite nanocrystals with high quality and excellent optoelectronic properties.

  • The proposed ligand engineering strategy firstly realized the suppression of emission thermal quenching effect in the organic-inorganic hybrid FAPbBr3 nanocrystals.

  • It was demonstrated that the FAPbBr3 based light-emitting diodes achieved a room temperature external quantum efficiency (EQE) of 21.9% at the luminance of 1580 cd m-2, and only presented less than 10% loss in EQE at a higher temperature of 343 K.



中文翻译:


配体工程实现了对纯绿色钙钛矿纳米晶体中温度淬灭的抑制,以实现高效和热稳定的电致发光



  • 利用芳香胺配体在室温下创新性地合成纯绿色 FAPbBr3 纳米晶,以细化具有高质量和优异光电性能的钙钛矿纳米晶体。


  • 所提出的配体工程策略首先实现了有机-无机杂化 FAPbBr3 纳米晶中发射热猝灭效应的抑制。


  • 结果表明,基于 FAPbBr3 的发光二极管在 1580 cd m-2 的亮度下实现了 21.9% 的室温外部量子效率 (EQE),并且在 343 K 的较高温度下仅表现出不到 10% 的 EQE 损耗。

更新日期:2024-11-29
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