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Deciphering Water Oxidation Catalysts: The Dominant Role of Surface Chemistry over Reconstruction Degree in Activity Promotion
Nano-Micro Letters ( IF 31.6 ) Pub Date : 2024-11-26 , DOI: 10.1007/s40820-024-01562-7 Li An, Jianyi Li, Yuanmiao Sun, Jiamin Zhu, Justin Zhu Yeow Seow, Hong Zhang, Nan Zhang, Pinxian Xi, Zhichuan J. Xu, Chun-Hua Yan
中文翻译:
破译水氧化催化剂:表面化学在活性促进中的主导作用超过重建度
更新日期:2024-11-26
Nano-Micro Letters ( IF 31.6 ) Pub Date : 2024-11-26 , DOI: 10.1007/s40820-024-01562-7 Li An, Jianyi Li, Yuanmiao Sun, Jiamin Zhu, Justin Zhu Yeow Seow, Hong Zhang, Nan Zhang, Pinxian Xi, Zhichuan J. Xu, Chun-Hua Yan
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Demonstrate that the key factor to determine the activity of reconstructed surfaces is the surface chemistry, instead of reconstruction degree using the popular perovskite LaNi1-xFexO3 oxides as model materials.
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Fe content can influence both the surface reconstruction degree, the activation degree, and the activity of reconstructed surfaces.
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The oxygen evolution reaction activity of reconstructed catalysts is primarily governed by the chemistry of the reconstructed surface species.
中文翻译:
破译水氧化催化剂:表面化学在活性促进中的主导作用超过重建度
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证明决定重建表面活性的关键因素是表面化学,而不是使用流行的钙钛矿 LaNi1-xFexO3 氧化物作为模型材料的重建程度。 -
Fe 含量可以影响表面重建程度、活化程度和重建表面的活性。 -
重构催化剂的析氧反应活性主要受重构表面物质的化学性质控制。