当前位置: X-MOL 学术Org. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Ultrafast Dual Activation of C(sp3)–H and C(sp2)–H Bonds in an Arc Plasma-Initiated Microdroplet
Organic Letters ( IF 4.9 ) Pub Date : 2024-11-19 , DOI: 10.1021/acs.orglett.4c03782
Yuanji Gao, Kaineng Huang, Ruiwen Wang, Yuanjiang Pan

This study demonstrates a method that utilizes arc plasma-induced microdroplet reactions to synthesize dual-activated products with C(sp3)–N and C(sp2)–O bonds starting from C–H bonds. This innovative process utilizes arc- and microdroplet-generated hydroxyl radicals and water dimer radical cations, opening new possibilities for the multisite derivatization of small molecules.

中文翻译:


电弧等离子体引发的微液滴中 C(sp3)–H 和 C(sp2)–H 键的超快双重激活



本研究展示了一种利用电弧等离子体诱导的微滴反应合成具有 C(sp3)–N 和 C(sp2)–O 键的双活化产物的方法,从 C–H 键开始。这种创新工艺利用电弧和微滴产生的羟基自由基和水二聚体自由基阳离子,为小分子的多位点衍生化开辟了新的可能性。
更新日期:2024-11-20
down
wechat
bug