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Front Cover: Cleavage of Carbodicarbenes with N2O for Accessing Stable Diazoalkenes: Two‐Fold Ligand Exchange at a C(0)‐Atom
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-11-19 , DOI: 10.1002/anie.202421515 Yijie He, Yichong Lyu, David Tymann, Patrick W. Antoni, Max M. Hansmann
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-11-19 , DOI: 10.1002/anie.202421515 Yijie He, Yichong Lyu, David Tymann, Patrick W. Antoni, Max M. Hansmann
Puzzling of ligands at C(0): In their Research Article (e202415228), Max M. Hansmann et al. demonstrate a new strategy to afford stable diazoalkenes by cleavage of a carbophosphinocarbene and carbodicarbenes with N2O. The follow-up N2/NHC exchange allows easy access to novel carbodicarbenes or cumulenic compounds. The combination of exchange reactions overall allows to “puzzle” the fragments at a C(0) atom.
中文翻译:
封面:用 N2O 裂解碳二卡宾以获得稳定的重氮碳烯:在 c(0)-原子处进行两重配体交换
C(0) 处配体的困惑:在他们的研究文章 (e202415228) 中,Max M. Hansmann 等人展示了一种通过用 N2O 裂解碳膦基卡宾和碳二卡宾来获得稳定重氮烯烃的新策略。后续的 N2/NHC 交换允许轻松获得新型碳二卡宾或立方化合物。交换反应的组合总体上允许在 C(0) 原子处“拼图”片段。
更新日期:2024-11-19
中文翻译:
封面:用 N2O 裂解碳二卡宾以获得稳定的重氮碳烯:在 c(0)-原子处进行两重配体交换
C(0) 处配体的困惑:在他们的研究文章 (e202415228) 中,Max M. Hansmann 等人展示了一种通过用 N2O 裂解碳膦基卡宾和碳二卡宾来获得稳定重氮烯烃的新策略。后续的 N2/NHC 交换允许轻松获得新型碳二卡宾或立方化合物。交换反应的组合总体上允许在 C(0) 原子处“拼图”片段。