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Inside Front Cover: Proton Intercalation into an Open‐Tunnel Bronze Phase with Near‐Zero Volume Change
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-11-19 , DOI: 10.1002/anie.202421490
Kosuke Kawai, Seong‐Hoon Jang, Yuta Igarashi, Koji Yazawa, Kazuma Gotoh, Jun Kikkawa, Atsuo Yamada, Yoshitaka Tateyama, Masashi Okubo

Proton intercalation of Mo3Nb2O14 bronze occurs with near-zero volume change, which arises from rotation and shrinkage of the flexible MOn framework (M = Mo, Nb) as reported by Kosuke Kawai et al. in their Research Article (e202410971). As a result, the Mo3Nb2O14 particle maintains high crystallinity after repeating proton (de)intercalation, which contributes to high Coulombic efficiency and long-term charge/discharge operation of an aqueous proton battery.

中文翻译:


封面内页:质子嵌入到开隧道青铜相中,体积变化接近零



Mo3Nb2O14 青铜的质子嵌入以接近零的体积变化发生,这是由柔性 MOn 框架 (M = Mo, Nb) 的旋转和收缩引起的,正如 Kosuke Kawai 等人在其研究文章 (e202410971) 中报告的那样。因此,Mo3Nb2O14 颗粒在重复质子(脱)嵌后保持高结晶度,这有助于水系质子电池的高库仑效率和长期充放电操作。
更新日期:2024-11-19
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